开放体系下有机质与有机碳、氢、氮损失动力学研究
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本文为国家油气专项之《华北前第三系油气资源战略调查及评价》项目中子课题《华北东部前第三系烃源岩研究》)资助的成果。


Weight Loss of Organic Matter, Organic Carbon, Hydrogen and Nitrogen in an Open System: Kinetic Approaches
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    摘要:

    本文对Ⅰ、Ⅱ、Ⅲ型干酪根的有机质、有机碳、氢、氮的损失进行了动力学研究,获得了Ⅰ、Ⅱ、Ⅲ型干酪根的总量、有机碳、氢以及氮质量损失动力学参数。此动力学参数可用于烃源灶的有机质总量,有机碳、氢、氮质量的恢复研究。在此基础上,结合专用Kinetics 软件,将此动力学参数应用于干酪根有机碳丰度、氢/碳和氮/碳原子比恢复系数计算。结果表明,在Ro介于0.47%~3.05%之间Ⅰ型干酪根有机碳丰度,碳、氢、氮总丰度,氢/碳和氮/碳原子比的恢复系数依次为1~1.89、1~1.96、1~2.13和1~0.56;Ⅱ型干酪根依次为0.98~1.05、1~1.06、1~1.89和1~0.66。Ⅲ型干酪根依次为1~0.82、1~0.83、1~1.59和1~0.56。因此在对高成熟—过成熟干酪根进行生烃评价时,Ⅰ、Ⅲ型干酪根残余有机碳丰度需要进行恢复,而Ⅱ型干酪根残余有机碳丰度不需要进行恢复。3种类型干酪根的H/C原子比均需要进行恢复。本文建立的Ⅰ、Ⅱ、Ⅲ型干酪根恢复动力学可用于计算开放体系热演化过程中残留干酪根或有机碳总量,在一定程度上弥补了以往着重考虑生出烃类演化的不足之处。

    Abstract:

    This paper mainly studied the weight loss of original organic matter, carbon, hydrogen and nitrogen of I, Ⅱ and Ⅲtypes kerogen by means of the chemical reaction kinetics, and the kinetics parameters of weight loss of kerogen and their organic carbon, hydrogen and nitrogen of Ⅰ, Ⅱ and Ⅲtypes kerogen are determined and calibrated by opensystem thermal simulating experiment. These kinetics parameters obtained can be used to calculate the amount of original organic matter, organic carbon, hydrogen and nitrogen in source rocks. Using the special kinetic software, the kinetic parameters then are applied to calculate the recovery coefficients of organic carbon abundance and atomic H/C and N/C ratios. The result shows that when Ro being between 0.47% and 3.05%, the coefficients of the recovery of the original organic carbon abundance, carbon, hydrogen and nitrogen, atomic H/C and N/C ratios for type I kerogen are from 1 to 1.89, from 1 to 1.96 , from 1 to 2.13, from 1 to 0.56, while the coefficients of the recovery for type Ⅱ kerogen are from 0.98 to 1.05 , from 1 to 1.06 , from 1 to 1.89, from 1 to 0.66 and for type Ⅲ kerogen are from 1 to 0.82, from 1 to 0.83, from 1 to 1.59, from 1 to 0.56, respectively. Thus, the abundance of residual organic carbon must be recovered when the potential of hydrocarbon generation are estimated for type Ⅰ and Ⅲ highmature and overmature kerogen, while the abundance of residual organic carbon need not be recovered for type Ⅱ kerogen. Atomic H/C ratios all need be recovered for all types of kerogen. In this paper, the recovery kinetics established for kerogen type Ⅰ, Ⅱ and Ⅲ may be used to calculate the residual organic matter or organic carbon during thermal evolution in an open system.

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张辉,彭平安,刘大永,张善文,秦艳,侯林慧.2008.开放体系下有机质与有机碳、氢、氮损失动力学研究[J].地质学报,82(5):710-720.
.2008. Weight Loss of Organic Matter, Organic Carbon, Hydrogen and Nitrogen in an Open System: Kinetic Approaches[J]. Acta Geologica Sinica,82(5):710-720.

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  • 收稿日期:2007-06-05
  • 最后修改日期:2007-10-29
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