内蒙古图古日格金矿床中碲化物的发现及其地质意义
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本文为国家自然科学基金项目(编号 42002099)、山东省重点研发计划项目(编号 2019GSF109101)、山东省自然科学基金青年基金项目(编号 ZR2018QD002)、山东省地质勘查项目(编号 SDGP370000202002001782)、国家自然科学基金项目(编号 41973048)资助的成果


Discovery and geological significance of tellurides in the Tugurige gold deposit in Inner Mongolia
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    摘要:

    图古日格金矿床是兴蒙造山带内的一个大型石英脉型金矿床,矿床的矿化与矿区内的钙碱性花岗质岩浆活动存在密切的成因联系。与钙碱性岩浆活动有关的富碲金矿床比较少见;具有富碲特征的金矿床,在兴蒙造山带内也鲜有报道。本次研究通过矿相学观察和电子探针分析,在图古日格金矿床矿石中发现了大量碲化物,包括碲金矿、六方碲银矿、碲金银矿和自然碲等,矿床中金的赋存形式主要为碲化物,其次为自然金和银金矿。图古日格金矿床的主成矿阶段(Ⅱ, 石英多金属硫化物阶段)从早到晚可划分为Ⅱ1、Ⅱ2和Ⅱ3三个亚阶段。Ⅱ1阶段的矿物组合为粗粒黄铁矿+六方碲银矿+碲金银矿+自然碲+粒状方铅矿;Ⅱ2阶段的矿物组合为细粒黄铁矿+碲金矿+碲金银矿+碲铅矿;Ⅱ3阶段的矿物组合为自然金+银金矿+脉状方铅矿。碲化物和硫化物共生组合显示,Ⅱ1阶段成矿流体的lgfS2为-13. 5 ~-10. 9,lgfTe2为-10. 5 ~-9. 4;Ⅱ2阶段成矿流体的lgfS2为-16. 7 ~-12. 4,lgfTe2为-11. 2~-9. 4。流体演化过程中发生的沸腾作用及含H2Te气相流体的冷凝作用是诱发该矿床大量金、银碲化物从成矿流体中沉淀并富集的主要机制,也是造成该矿床成矿流体中的碲含量不均匀,并且出现自然碲+硫化物等不平衡矿物组合的原因。

    Abstract:

    The Tugurige gold deposit is a large tonnage quartz- vein type deposit in the western part of the Xing'an- Mongolia Orogenic Belt (XMOB). The gold mineralization and calc- alkalic granitic magmatism of this deposit have very close genetic relationships. Te- rich gold deposits associated with calc- alkalic granitic magmatism are relatively rare, and this kind of Te- rich gold deposits is rarely reported in the XMOB. Based on optical microscope and electron probe micro- analysis (EPMA), for the first time a large number of the tellurides were discovered in the ore samples of the Tugurige gold deposit, such as calaverite, stutzite, petzite and native tellurium. The gold and silver of this deposit are primarily occurring as Au- and Ag- tellurides, with a small amount of native gold and electrum. The main mineralization stage (Ⅱ, auriferous quartz- polymetallic sulfide stage) of this deposit can be divided into three sub- stages from early to late, namely,Ⅱ1, Ⅱ2, and Ⅱ3- stage. The mineral assemblages of Ⅱ1, Ⅱ2, and Ⅱ3- stage are coarse pyrite- stutzite- petzite- native tellurium- galena, fine- grained pyrite- calaverite- petzite- altaite, and native gold- electrum- galena, respectively. The mineral assemblage characteristics indicate that, in Ⅱ1- stage of mineralization, the lgfS2 and lgfTe2 values of ore forming fluids ranged from -13. 5 to -10. 9 and from -10. 5 to -9. 4. The lgfS2 and lgfTe2 values of ore forming fluids in Ⅱ2- stage ranged from -16. 7 to -12. and from -11. 2 to -9. 4, respectively. Fluid boiling and condensation of H2Te- bearing vapors were the dominant controls on precipitation of the Au and Ag telluride ores, and occurrence of inhomogenous native tellurium- sulfide mineral assemblages.

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丁成武,戴盼,江思宏,郝金华,张照录,刘琦,彭云彪,张更信.2022.内蒙古图古日格金矿床中碲化物的发现及其地质意义[J].地质学报,96(7):2450-2463.
DING Chengwu, DAI Pan, JIANG Sihong, HAO Jinhua, ZHANG Zhaolu, LIU Qi, PENG Yunbiao, ZHANG Gengxin.2022. Discovery and geological significance of tellurides in the Tugurige gold deposit in Inner Mongolia[J]. Acta Geologica Sinica,96(7):2450-2463.

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  • 收稿日期:2021-04-23
  • 最后修改日期:2021-06-10
  • 录用日期:2021-06-11
  • 在线发布日期: 2021-08-26
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