寒武系古流体地球化学特征及其对页岩气保存的指示意义 ——以中扬子地区寒武系页岩气发现井宜地2井为例
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本文为国家科技重大专项(编号 2016ZX05034001-002)、中国地质调查项目(编号 DD20179615)资助成果


Characteristics of Cambrian paleofluid geochemistry and its implications to shale gas preservation --take well Yidi 2 in Yichang area as an example
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    摘要:

    保存条件是中扬子地区页岩气富集的关键因素之一,宜地2井是中扬子寒武系页岩气发现井,通过对该井全井段岩芯裂缝古流体的地球化学分析,探讨了寒武系古流体成因和对水井沱组页岩气保存条件的指示意义。结果认为:① 覃家庙组膏岩层之上方解石脉缺少Fe2+、Mn2+,且δ13C和δ18O值较围岩偏负,指示其形成于氧化的环境,石牌组方解石脉δ13C偏负,黄铁矿脉δ34S值与膏盐相似,表明其成因与TSR密切相关;水井沱组脉体δ13C和δ18O与围岩相似,形成于封闭的环境。② 方解石脉包裹体群SO42-、Ca2+、Mg2+含量整体上由覃家庙组向上向下分别递减,钠氯系数以水井沱组最低,整体上向上升高,表明覃家庙组是高盐度卤水的主要来源,水井沱组受外来流体影响弱;包裹体水溶液δD和δ18O也指示娄山关组、石牌组方解石脉成因分别与大气水、TSR相关。③ 古流体地球化学研究表明宜昌地区页岩气保存条件整体较好,页岩气散失的主要通道是垂直裂缝,页岩气保存条件好与膏盐盖层发育、后期构造破坏弱、脉体对裂缝的及时封闭以及白垩系盖层等因素密切相关。

    Abstract:

    We analysis the paleofluid geochemical features of fractures from Yidi-2 Well,the discovery well of Cambrian shale gas. The forming environment of paleofluids and its indications to shale gas preservation of Shuijingtuo Formation are further discussed,as preservation conditions are key factors for shale gas enrichment in the middle Yangtze. The following results are obtained. The calcite veins above Qinjiamiao Formation lack of Fe2+, Mn2+ and δ13C values and δ18O values smaller than surrounding rocks mean the oxidation environment. Calcite veins δ13C lighter than surrounding rocks and pyrite δ34S closed to gypsum indicate they are productions of TSR. The calcite veins of Shuijingtuo Formation and Yanjiahe Formation formed in enclosed environment with δ13C and δ18O closed to surrounding rocks. SO42-, Ca2+, Mg2+ contents of vein inclusions decrease from Qinjiamiao Formation to upper and deeper layers, the lowest (rNa+/rCl-) value in Shuijingtuo Formation indicate that Qinjiamiao Formation is the main source of high-salinity brine and Shuijingtuo Formation is hardly affected by the external fluids. δD and δ18O also indicate the veins in Loushanguan Formation and Shipai Formation formed with meteoric water an TSR respectively. The preservation condition in Yichang area is generally good for shale gas, the vertical fractures were ways to shale gas losing. The gypsum cover, weak tectonic movement in later stage, veins plugging fracture, rapid deposition of Cretaceous have relation with good preservation condition.

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刘安,陈孝红,肖七林,黄惠兰,包汉勇,危凯,曾雄伟,王传尚.2022.寒武系古流体地球化学特征及其对页岩气保存的指示意义 ——以中扬子地区寒武系页岩气发现井宜地2井为例[J].地质学报,96(7):2573-2584.
LIU An, CHEN Xiaohong, XIAO Qilin, HUANG Huilan, BAO Hanyong, WEI Kai, ZENG Xiongwei, WANG Chuanshang.2022. Characteristics of Cambrian paleofluid geochemistry and its implications to shale gas preservation --take well Yidi 2 in Yichang area as an example[J]. Acta Geologica Sinica,96(7):2573-2584.

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  • 收稿日期:2021-04-08
  • 最后修改日期:2021-05-27
  • 录用日期:2021-05-28
  • 在线发布日期: 2021-06-23
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