川西坳陷中段须家河组四段砂岩中碳酸盐胶结物碳、氧同位素特征及成因探讨
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Carbon and oxygen isotope characteristics and genesis of carbonate cements in sandstone of the 4th Member of the Xujiahe Formation in the central western Sichuan depression, Sichuan basin, China
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    摘要:

    碳酸盐胶结物是川西坳陷须家河组四段砂岩中最常见的成岩矿物。应用激光微区取样碳、氧同位素测试方法,对研究区须四段砂岩中不同类型的碳酸盐胶结物的碳、氧同位素特征进行了精细分析,结合岩相学特征和流体包裹体分析,查明了不同类型碳酸盐胶结物的形成时间和成因机制。研究表明,研究区须四段砂岩中发育Ⅰ、Ⅱ、Ⅲ三期碳酸盐胶结物。第Ⅰ期方解石的δ13CPDB值为-0. 13‰~1. 53‰,δ18OPDB值为-9. 92‰~-6. 41‰;第Ⅱ期方解石的δ13CPDB值为-2. 44‰~1. 85‰,δ18OPDB值为-13. 97‰~-10. 06‰;第Ⅲ期方解石的δ13CPDB值为-5. 34‰~0. 75‰,δ18OPDB值为-16. 55‰~-14. 44‰,第Ⅲ期白云石的δ13CPDB值为-0. 97‰~-0. 81‰,δ18OPDB值为-13. 32‰~-12. 91‰。从早期到晚期,碳酸盐胶结物的碳、氧同位素均表现为逐渐变轻,说明其沉淀温度逐渐升高,受有机流体影响逐渐加深。第Ⅰ期碳酸盐胶结物形成于晚三叠世末,储层处于浅埋藏阶段,是从早期过饱和碱性孔隙流体中直接沉淀出来的,其“碳”源主要来自沉积水中溶解的CO32-。第Ⅱ期碳酸盐胶结物形成于早侏罗世,沉淀温度约45~70℃,其形成有少量有机流体的参与,有机轻“碳”、原始孔隙水中溶解的“碳”以及少量溶蚀作用释放出的重“碳”共同为该期碳酸盐胶结物提供“碳”源。第Ⅲ期碳酸盐胶结物形成于晚侏罗世,沉淀温度约100~140℃,其成因与有机酸性流体关系密切,有机成因的轻“碳”和部分由溶蚀作用释放的重“碳”是该期方解石的主要“碳”源;而该期白云石的沉淀受砂岩中碳酸盐岩岩屑溶蚀的控制更明显,由溶蚀作用产生的重“碳”是其主要“碳”源。

    Abstract:

    Carbonate cements are the most common diagenetic mineral in the sandstone of the 4th Member of the Xujiahe Formation (T3x4) in western Sichuan basin. The carbon and oxygen isotopes of different types of carbonate cements were analyzed using laser micro- sampling, in the T3x4 in the study area. Combined with petrographic characteristics and fluid inclusion analysis, the formation periods and genetic mechanism of different types of carbonate cements have been identified. Carbonate cements developed in the sandstone of T3x4 in three phases. The δ13CPDB values of the calcite in Phase Ⅰ are -0. 13‰~1. 53‰, while the δ18OPDB values are -9. 92‰~-6. 41‰. The δ13CPDB values of the calcite in Phase Ⅱ are -2. 44‰~1. 85‰, and the δ18OPDB values are -13. 97‰~-10. 06‰. The δ13CPDB value of the calcite in Phase Ⅲ is -5. 34‰~0. 75‰, and the δ18OPDB value is -16. 55‰~-14. 44‰. The δ13CPDB values of dolomite in Phase Ⅲ are -0. 97‰~-0. 81‰, and the δ18OPDB values are -13. 32‰~-12. 91‰. The carbon and oxygen isotopes of carbonate cements gradually became lighter from early to late, indicating that the precipitation and temperature increased, and the influence of organic fluids becomes stronger. The Phase I carbonate cement formed at the end of the Late Triassic (in the shallow burial stageof the reservoir) was directly precipitated from the supersaturated alkaline pore fluid derived from sedimentary water, and the source of “C” mainly comes from dissolved CO32- in sedimentary water. The Phase Ⅱ carbonate cement precipitated in the Early Jurassic (temperature about 45~70℃). Its formation is slightly affected by organic fluid. Its “C” sources include (1) light “C” from organic fluids, (2) “C” form original pore water, and (3) heavy “C” released by weak dissolution. The Phase Ⅲ carbonate cement formed in the Late Jurassic (temperature about 100~140℃), which is closely related to the injection of organic acid fluid. The main “C” sources of the Phase Ⅲ calcite are organic light “C” and part of the heavy “C” released by dissolution. The origin of the Phase Ⅲ dolomite is obviously controlled by the dissolution of carbonate rock debris in sandstone. The main “C” source is the heavy “C” form dissolution.

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张庄,庞江,杨映涛,操延辉,戚明辉,张烨毓,张玲,马森.2022.川西坳陷中段须家河组四段砂岩中碳酸盐胶结物碳、氧同位素特征及成因探讨[J].地质学报,96(6):2094-2106.
Zhang Zhuang, Pang Jiang, Yang Yingtao, Cao Yanhui, Qi Minghui, Zhang Yeyu, Zhang Ling, Ma Sen.2022. Carbon and oxygen isotope characteristics and genesis of carbonate cements in sandstone of the 4th Member of the Xujiahe Formation in the central western Sichuan depression, Sichuan basin, China[J]. Acta Geologica Sinica,96(6):2094-2106.

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  • 收稿日期:2021-03-12
  • 最后修改日期:2021-06-09
  • 录用日期:2021-06-09
  • 在线发布日期: 2022-06-27
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