短波红外光谱技术在斑岩-高硫化型浅成低温热液矿床中的应用——以西藏铁格隆南超大型铜(金)矿床为例
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本文为国家重点研发计划项目(编号2016YFC0600308)、国家自然科学基金项目(编号41902097)、西藏自治区科技计划项目(编号XZ201901- GB- 24)和中国地质科学院基本科研业务费专项经费项目(编号SYSCR2019- 02)联合资助的成果。


Application of short- wavelength infrared spectroscopy in porphyry- epithermal system: a case study of Tiegelongnan super- large copper (gold) deposit, Tibet
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    摘要:

    铁格隆南铜(金)矿是西藏首例超大型斑岩- 高硫化型浅成低温热液矿床。准确划分该矿床的蚀变分带对于后续的找矿勘探具有重要意义。本文主要运用短波红外光谱分析技术对西藏铁格隆南矿床进行蚀变矿物信息提取,同时利用X射线衍射辅助矿物识别;并结合岩相学和电子探针分析,对主要蚀变矿物绢云母的光谱特征进行系统梳理,构建铁格隆南矿区蚀变分带模型,探讨其勘查指示意义。结果表明:短波红外光谱清晰识别出高岭石、明矾石、地开石、叶腊石、绢云母、石膏、水铝石、蒙脱石8种蚀变矿物。根据蚀变矿物组合空间分布特征,从斑岩中心向外,可划分出钾硅酸盐化、绢英岩化、青磐岩化蚀变,在中浅部被高级泥化蚀变广泛叠加。矿区广泛产出绢云母,其主吸收谷波长介于2196~2215 nm(平均值为2206. 6 nm)之间,且深部钾硅酸盐化带与绢英岩化带中的绢云母主吸收谷波长差异明显,钾硅酸盐化带中波长可大于2210 nm,可能是绢英岩化蚀变对钾硅酸盐化蚀变叠加改造的结果,绢英岩化带则集中于2206~2208 nm区间。绢云母1400 nm吸收峰波长(Pos1400值)和绢云母Al- OH的吸收深度(Dep2200值)与铜矿化强度呈现良好的耦合关系,可作为后续斑岩- 浅成低温热液矿床勘查评价的重要指示标志。绢云母族矿物Al- OH吸收峰(Pos2200值)较小(<2203 nm)且结晶度指数值越大(>5. 5)的区域揭示铁格隆南矿床的热液成矿中心主要位于ZK2404的深部。

    Abstract:

    The Tiegelongnan copper (gold) deposit is the first porphyry- high sulfide type- epithermal deposit in Tibet. Figuring out the accurate alteration zonation of the deposit is pivotal to the subsequent exploration. In this paper, we use the short wavelength infrared spectroscopy (SWIR) to extract the altered mineral information of Tiegelongnan deposit, and use X- ray diffraction (XRD) as a supplementary method for mineral identification. Combined with petrography, electron probe microanalysis (EPMA), and the spectral parameters of sericite, the alteration zonation model of Tiegelongnan ore district was constructed, and its significance for exploration was evaluated. The results show that eight typical alteration minerals (kaolinite, alunite, dickite, pyrophyllite, muscovite, gypsum, diaspore and montmorillonite) can be identified by the SWIR. Meanwhile, according to the spatial distribution of the alteration mineral assemblage, from the center of porphyry to the outside, the alteration includes potassium silicate alteration, sericite- quartz alteration and propylitization alteration, which are widely superimposed by later argillic alteration in the middle and shallow part. Sericite was widely spread in mineral area. Its main absorption valley spectral wavelength ranges from 2196. 4 nm to 2214. 8 nm (average value is 2206. 6 nm), the main absorption valley wavelengths of sericite in the deep potassium silicate alteration zone and sericite alteration zone are obviously different. The wavelength of sericite in the potassium silicate alteration zone in the deep part can be greater than 2210 nm, while sericite in sericite- quartz alteration has Pos2200 2206 to 2208 nm. The absorption peak wavelength of sericite at 1400 nm (Pos1400) and the absorption depth of sericite Al- OH (Dep2200) values of muscovite have a good positive correlation with the copper mineralization intensity, which can be used as an indicator for subsequent exploration and evaluation of porphyry epithermal deposits. We concluded that the elevated Pos2200 (<2203 nm) and SWIR- IC values (>5. 5) can indicate that the hydrothermal mineralization center of Tiegelongnan deposit is mainly located in the deep of ZK2404.

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唐楠,林彬,李玉彬,王艺云,李佳俊.2021.短波红外光谱技术在斑岩-高硫化型浅成低温热液矿床中的应用——以西藏铁格隆南超大型铜(金)矿床为例[J].地质学报,95(8):2613-2627.
Tang Nan, Lin Bin, Li Yubin, Wang Yiyun, Li Jiajiun.2021. Application of short- wavelength infrared spectroscopy in porphyry- epithermal system: a case study of Tiegelongnan super- large copper (gold) deposit, Tibet[J]. Acta Geologica Sinica,95(8):2613-2627.

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  • 收稿日期:2020-12-20
  • 最后修改日期:2021-01-22
  • 录用日期:2021-01-23
  • 在线发布日期: 2021-05-27
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