内蒙古赤峰双尖子山银多金属矿床成矿流体来源及金属沉淀机制探讨
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本文为中国地质调查局中国矿产地质志项目(编号DD20160346、DD20190379)、内蒙古地勘基金内蒙古锡林浩特市- 巴林左旗铜多金属矿成矿规律及选区研究项目(2015- 01- YS01)和中央级公益性科研院所基本科研业务费项目(编号JYYWF20183701、JYYWF20183704)联合资助成果。


The source of ore- forming fluid and mechanism of metal precipitation in the Shuangjianzishan Ag- polymetallic deposit in Chifeng, Inner Mongolia
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    摘要:

    双尖子山超大型银多金属矿床是大兴安岭成矿带最具代表性的热液型银矿床,也是目前亚洲最大银矿。该矿床热液作用可划分为Ⅰ、Ⅱ两期,第Ⅰ期又可划分三个成矿阶段,依次为成矿阶段(Ⅰ- 1)(主要为黄铁矿+方铅矿+闪锌矿+银矿物+石英组合,分布在北西走向矿脉)→成矿阶段(Ⅰ- 2)(主要为方铅矿+银矿物+闪锌矿+石英+方解石组合,分布在北北东走向矿脉)→成矿阶段(Ⅰ- 3)(含金石英+方解石脉组合,分布在近东西走向矿脉)。第Ⅱ期为胶结硫化物脉的无矿石英脉,主要是石英+少量方解石组合。该矿床流体包裹体以L型和V型为主,总体属于中低温- 低盐度流体。成矿阶段(Ⅰ- 1)流体包裹体均一温度介于171℃~280℃之间,平均228℃,盐度介于0. 53%~12. 73%(NaCl eqv)之间,平均3. 48%(NaCl eqv);成矿阶段(Ⅰ- 2)流体包裹体均一温度介于109. 3℃~258. 0℃之间,平均193. 3℃,盐度介于0. 18%~22. 38%(NaCl eqv)之间,平均4. 20%(NaCl eqv);第Ⅱ期热液流体包裹体均一温度介于238. 7℃~362. 9℃之间,平均275. 9℃,盐度介于0. 35%~2. 24%(NaCl eqv)之间,平均1. 05%(NaCl eqv)。方解石δ13 C介于-11‰~-7. 4‰,δ 18 O SMOW 介于1‰~4. 5‰;石英和方解石δD H 2O 变化于-145‰ ~-65‰,δ 18 O H 2O 变化于-12. 5‰~4. 6‰,表明流体为岩浆水和大气降水的混合来源;金属硫化物 40 Ar/ 36 Ar 值介于294. 75~303. 92, 3 He/ 4 He值介于0. 25~0. 81Ra,显示壳源流体特征。双尖子山矿床成矿流体具有脉冲式活动、多阶段演化和多来源特点,成矿流体具有从相对的高温高盐度向低温低盐度演化规律。岩浆水与循环大气降水的混合作用可能是本矿床金属沉淀的主要机制。双尖子山矿床属于与壳源岩浆活动有关的中浅成- 中低温热液型银多金属矿床。

    Abstract:

    The Shuangjianzishan super- large Ag- polymetallic deposit is the most representative hydrothermal silver deposit in the Daxing'anling metallogenic belt and the largest silver deposit discovered in Asia. The hydrothermal mineralization of this deposit can be divided into two periods, Period I and Period II. Period I can be further divided into three stages: stage I- 1 (pyrite+galena+sphalerite+silver bearing mineral+quartz assemblage hosted witin NW- trending veins), stage I- 2 (galena+silver bearing mineral+sphalerite+quartz+calcite assemblage hosted within NNE- trending veins), and stage I- 3 (Au- bearing quartz+calcite vein assemblage within near- EW trending veins. Period II is nonmineralized quartz veins mainly being quartz+calcite assemblage. The fluid inclusions in the deposit are dominated by L- type and V- type, generally belonging to medium- low temperature, low salinity fluid. The homogenization temperature of stage I- 1 ore- forming fluid inclusions ranges from 171℃ to 280℃, with an average of 228℃,and salinity of 0.53%~12.73% (NaCl eqv ) with an average of 3.48% (NaCl eqv ). The homogenization temperature of stage I- 2 ore- forming fluid inclusions ranges from 109.3 ℃ to 258.0℃ with an average of 193.3℃ and salinity of 0.18%~22.38% (NaCl eqv ) with an average of 4.20% (NaCl eqv ). The homogenization temperatures of fluid inclusions in period II range from 238.7℃ to 362.9℃, with an average of 275.9℃ and salinity of 0. 35%~2.24% (NaCl eqv ) with an average of 1.05% (NaCl eqv ). δ13 C and δ18 O SMOW of calcite range from -11‰ ~-7.4‰ and 1‰~4.5‰ respectively. δD H 2O and δ18 O H 2O of quartze and calcite vary from -145‰ to -65‰ and from -12.5‰ to 4.6‰, indicating that the ore- forming fluid is a mixed source. The 4 0 Ar/ 36 Ar ratio of metal sulfide ranges from 294.75 to 303.92 and the 3 He/ 4 He ratio ranges from 0.25 to 0.81 Ra, suggesting its origin of crustal source. The ore- forming fluids of the Shuangjianzishan deposit have the characteristics of multiply pulsed, multi- stage evolution and multi- source, presenting an evolution trend from relatively high temperature and high salinity to low temperature and low salinity. The mixing of initial magmatic water and atmospheric precipitation may be the main mechanism of metal precipitation in this deposit. The Shuangjianzishan deposit is a meso- epithermal Ag- polymetallic deposit related to crustal magmatism.

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江彪,张通,陈毓川,黄凡,武广,孙洪军,李治远,李雪娇,闫洁.2019.内蒙古赤峰双尖子山银多金属矿床成矿流体来源及金属沉淀机制探讨[J].地质学报,93(12):3166-3182.
JIANG Biao, ZHANG Tong, CHEN Yuchuan, HUANG Fan, WU Guang, SUN Hongjun, LI Zhiyuan, LI Xuejiao, LI Xuejiao.2019. The source of ore- forming fluid and mechanism of metal precipitation in the Shuangjianzishan Ag- polymetallic deposit in Chifeng, Inner Mongolia[J]. Acta Geologica Sinica,93(12):3166-3182.

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  • 收稿日期:2019-09-25
  • 最后修改日期:2019-11-05
  • 录用日期:2019-12-11
  • 在线发布日期: 2019-12-12
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