东秦岭地区碳酸岩型钼- 铀多金属矿床成矿时代:来自LA- ICP- MS独居石U- Pb和辉钼矿Re- Os年龄的证据
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本文为中国地质调查项目(编号DD20160129;DD20190119;DD20201148)和国家自然科学基金项目(编号41502082)联合资助成果。


Metallogenic epoch of the carbonatite- type Mo- U polymetallic deposit in east Qinling: evidence from the monazite LA- ICP- MS U- Pb and molybdenite Re- Os isotopic dating
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    摘要:

    东秦岭地区碳酸岩型钼- 铀多金属矿床主要包括华阳川铀多金属矿、黄龙铺和黄水庵钼矿等。其中,华阳川矿床为近期取得勘查突破的一例以U、Nb、Pb为主并伴生稀土元素的超大型铀多金属矿床;黄龙铺钼矿为东秦岭钼矿带中成矿类型最为独特的大型钼矿床。为了精确获得东秦岭地区碳酸岩型钼- 铀多金属成矿时代,本研究采用辉钼矿Re- Os法和LA- ICP- MS独居石U- Pb法,分别对黄龙铺大石沟矿床的辉钼矿、秦岭沟矿床和华阳川矿床含矿碳酸岩脉中的独居石进行测定。结果表明,黄龙铺地区大石沟钼矿辉钼矿Re- Os等时线年龄为221. 3±8. 4Ma(MSWD=10. 9);秦岭沟钼矿碳酸岩中独居石LA- ICP- MS Tera- Wasserburg年龄为207±11Ma(MSWD=3. 7, n =38),华阳川铀多金属矿LA- ICP- MS独居石Tera- Wasserburg年龄为222. 5±6. 7Ma(MSWD=1. 8, n =37),表明该地区碳酸岩中的钼矿化和铀多金属矿化均形成于晚三叠世。综合分析认为,东秦岭地区发育于碳酸岩中的黄龙铺钼矿田、华阳川铀多金属矿是同一成矿系列的产物,碳酸岩型钼- 铀多金属的成矿金属可能来源于地幔,这类碳酸岩可能是秦岭地区印支期造山后伸展环境下的产物。

    Abstract:

    The carbonatite- type Mo- U polymetallic deposits in the eastern Qinling mainly comprises of the Huayangchuan U polymetallic, the Huanglongpu Mo, and the Huangshuian Mo deposits. The Huayangchuan is a super- large U- Nb- Pb deposit accompanying rare- earth elements, and the Huanglongpu is a unique large scale Mo deposit in the eastern Qinling molybdenum belt. In this paper, we use molybdenite Re- Os dating and LA- ICP- MS monazite U- Pb dating to precisely determine the timing of the carbonate- type Mo- U polymetallic mineralization in the eastern Qinling. The Re- Os dating of molybdenite samples from the Dashigou Mo deposit yields a Re- Os isochron age of 221. 3±8. 4 Ma. The LA- ICP- MS monazite U- Pb dating in carbonate dyke from the the Qinlinggou Mo deposit and the Huayangchuan U polymetallic deposit yielded Tera- Wasserburg concordant ages of 207±11 Ma (MSWD=3. 7, n =38) and 222. 5±6. 7 Ma (MSWD=1. 8, n =37), respectively. These ages show that U polymetallic and Mo mineralization in carbonates occurred in the Late Triassic. In conclusion, the Huanglongpu Mo orefield and Huayangchuan U polymetallic deposit, which occurred in carbonatites, were formed in the same mineralization series. The ore- forming materials of carbonatite- type Mo- U polymetallic deposit may derived from the mantle, and the carbonatites may be the products of the post- orogenic extensional setting in the Qinling Orogenic Belt.

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王佳营,李志丹,张祺,李超,谢瑜,李光耀,曾威,丁宁.2020.东秦岭地区碳酸岩型钼- 铀多金属矿床成矿时代:来自LA- ICP- MS独居石U- Pb和辉钼矿Re- Os年龄的证据[J].地质学报,94(10):2946-2964.
WANG Jiaying, LI Zhidan, ZHANG Qi, LI Chao, XIE Yu, LI Guangyao, ZENG Wei, DING Ning.2020. Metallogenic epoch of the carbonatite- type Mo- U polymetallic deposit in east Qinling: evidence from the monazite LA- ICP- MS U- Pb and molybdenite Re- Os isotopic dating[J]. Acta Geologica Sinica,94(10):2946-2964.

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  • 收稿日期:2019-08-19
  • 最后修改日期:2019-12-04
  • 录用日期:2019-12-18
  • 在线发布日期: 2019-12-18
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