中条山地区铜矿壳源流体成矿:来自铜矿峪、胡家峪流体包裹体氦、氩同位素的证据
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本文为中国地质调查局地质大调查项目(编号 DD20160129,DD20190119)、国家自然科学基金项目(编号 41502082)联合资助成果。


Crustal- fluid origin for copper mineralization in the Zhongtiaoshan region:evidence of He and Ar isotopes from fluid inclusions in the Tongkuangyu and Hujiayu deposits
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    摘要:

    山西中条山地区是我国重要的铜成矿带,发育铜矿峪斑岩型铜矿和“胡(家峪)篦(子沟)”型铜矿。本文对铜矿峪铜矿的黄铁矿和黄铜矿、胡家峪铜矿的黄铁矿开展了流体包裹体中的He、Ar同位素组成研究。铜矿峪黄铁矿、黄铜矿流体包裹体中的 4 He含量为46. 23×10 -8 ~1195. 75×10 -8 cm 3 STP/g, 3 He/ 4 He比值为0. 01~0. 06Ra, 40 Ar含量为1. 69×10 -8 ~74. 11×10 -8 cm 3 STP/g; 40 Ar/ 36 Ar为407~2327. 8。胡家峪黄铁矿流体包裹体中 4 He含量为314. 06×10 -8 ~3815. 87×10 -8 cm 3 STP/g; 3 He/ 4 He为0. 003~0. 014Ra , 40 Ar含量为25. 62×10 -8 ~761. 51×10 -8 cm 3 STP/g; 40 Ar/ 36 Ar 值为936. 1~4108. 6。中条山地区铜矿床 3 He/ 4 He值明显指示壳源He特征,铜矿峪、胡家峪样品中幔源He的含量介于0~0. 56%之间,幔源He对成矿的贡献可忽略不计。在成矿流体的 40 Ar/ 36 Ar- 3 He/ 4 He和 40 Ar*/ 4 He 3 He/ 4 He关系图解中所有样品均投点于壳源流体区域,显示Ar为地壳来源。因此,中条山地区大规模成矿作用以壳源流体成矿为主,并未发现幔源流体参与成矿的踪迹。

    Abstract:

    The Zhongtiaoshan region in Shanxi Province is an important copper metallogenic belt in China, which hosts the Hujiayu porphyry copper deposit and the ‘HujiayuBizigou’type copper deposit.In this paper, we analyzed the helium and argon isotopic compositions of fluid inclusions from pyrite and chalcopyrite in Tongkuangyu and pyrite in Hujiayu.For the Tongkuangyu deposit, 4 He content of fluid inclusions ranges from 46. 23×10 -8 cm 3 STP/g to 1195. 75×10 -8 cm 3 STP/g, with 3 He/ 4 He ratios between 0. 01 Ra to 0. 06 Ra; 40 Ar content varies from 1. 69×10 -8 cm 3 STP/g to 74. 11×10 -8 cm 3 STP/g, with 40 Ar/ 36 Ar ratios of 407 to 2327. 8.For the Hujiayu deposit, 4 He content, 3 He/ 4 He ratios, 40 Ar content and 40 Ar/ 36 Ar ratios range from 314. 06×10 -8 cm 3 STP/g to 3815. 87×10 -8 cm 3 STP/g, 0. 003 Ra to 0. 014 Ra, 25. 62×10 -8 cm 3 STP/g to 761. 51 ×10 -8 cm 3 STP/g and 963. 1 to 4108. 6, respectively.The 3 He/ 4 He ratios of the Zhongtiaoshan copper deposit show typical feature of crustal He.The mantlesourced He contents of samples in the Tongkuangyu and Hujiayu copper deposits range from 0 to 0. 56%, contribution of which to mineralizaiton can be ignored.The diagrams of 40 Ar/ 36 Ar vs.R/Ra as well as 40 Ar * / 4 He vs.R/Ra show that all the samples fall into the crustal source area, suggesing Ar crustal origin.Therefore, the largescale copper mineralization in the Zhongtiaoshan region resulted from crustal fluid, without involvement of mantle fluid into mineralization.

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李志丹,李效广,曾威,张超,王佳营,薛生升.2019.中条山地区铜矿壳源流体成矿:来自铜矿峪、胡家峪流体包裹体氦、氩同位素的证据[J].地质学报,93(9):2245-2259.
LI Zhidan, LI Xiaoguang, ZENG Wei, ZHANG Chao, WANG Jiaying, XUE Shengsheng.2019. Crustal- fluid origin for copper mineralization in the Zhongtiaoshan region:evidence of He and Ar isotopes from fluid inclusions in the Tongkuangyu and Hujiayu deposits[J]. Acta Geologica Sinica,93(9):2245-2259.

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  • 收稿日期:2019-06-09
  • 最后修改日期:2019-06-22
  • 录用日期:2019-08-01
  • 在线发布日期: 2019-08-22
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