北山南部富锰岩石的发现及成因
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本文为中国地质调查局 “天山- 北山成矿带那拉提营毛沱地区地质矿产调查(编号:121201011000150002)” 项目,“新疆若羌白山地区1∶5万K46E019015、K46E019016、K46E020014、K46E020015四幅地质矿产综合调查”项目(编号:12120115021501)资助。


The discovery and genesis of the manganeserich rocks in the southern Beishan Mountain, China
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    摘要:

    北山南部地区进行矿产地质调查,以查明矿产类型和分布情况。在长城系石英片岩中发现富锰岩石,其野外产出厚度0. 5m,沿走向延伸4. 6m,呈扁豆体形状,其上部为含锰灰岩与含锰磁铁石英岩,围岩为石英片岩。岩石颜色为黑色,致密块状,半金属光泽,染手。对采集的富锰岩石样品,化学定量分析,Mn为29. 68%、30. 59%、27. 72%,Mn/Fe分别为9. 2、9. 8、8. 7,P/Mn分别为0. 00071、0. 00078、0. 00076。含锰灰岩Mn为4. 62%~4. 92%,含锰磁铁石英岩Mn为0. 52%~1. 54%。样品X射线衍射分析、物相分析与电子探针分析结果表明,矿物组成有菱锰矿(Rhodochrosite,MnCO 3 )、软锰矿(Pyrolusite,MnO 2 )、水锰矿\[Manganite,MnO 2 ·Mn(OH) 2 \]、锰铝榴石\[Spessartine,Mn 3 Al 2 (SiO 4 ) 3 \]、锰钙辉石\[Johannsenite,CaMn(SiO 3 ) 2 \]、蔷薇辉石\[Rhodonite,(Mn,Fe,Ca) 5 Si 5 O 15 \]、锰橄榄石(Tephroite,Mn 2 SiO 4 )等。笔者发现的富锰岩石与国外锰矿床的矿石相比较,其特征和主要矿物组合,类似于古元代巴西变质锰矿床、泥盆纪南乌拉尔变质锰矿床和白垩纪日本变质锰矿床。从野外富锰岩石产出的地质特征,结合室内样品测试分析结果,并对这些特殊矿物和锰含量的研究认为,①富锰岩石可能是在敦煌古老地块边部滨浅海环境沉积形成,锰的来源可能与陆源和热液流体有关;②在后期区域变质作用和接触变质作用中,砂岩变质成为石英片岩,灰岩中的菱锰矿、软锰矿和水锰矿部分变质成为含锰硅酸盐;③之后可能又发生了表生风化作用形成现今的富锰岩石;④富锰岩石的发现表明,该地区具有形成锰矿床的成矿地质环境。

    Abstract:

    A survey was conducted in the southern Beishan Mountain to ascertain mineral ypes and distribution. A manganeserich rock bed, 0. 5 m thick at the surface, extending 4. 6 m in the horizontal direction with a bean shape has been discovered in the quartz schist in Changchengian System stratum. Its upper part is Mnlimestone and Mnmagnetite quartz rock, sandwiched between Quartz schist. The manganese ore is black, bulky, semimetallic luster, and also occurs as dirty bands. The results of the manganeserich rock samples by quantitative chemical analysis are Mn 29. 68%, 30. 59%, 27. 72%,Mn/Fe 9. 2, 9. 8, 8. 7,P/Mn is 0. 00071, 0. 00078, 0. 00076. The Mn content of Mnlimestone is 4. 62~4. 92% and of Mnmagnetite quartz rock is 0. 52~1. 54%. Moreover, based on the phase analysis tests, the Xray diffraction the electron probe data, and the microscopic identification, the important minerals are Rhodochrosite (MnCO3), Pyrolusite (MnO2), Manganite(MnO2·Mn(OH)2),Spessartine (Mn3Al2(SiO4)3), Johannsenite (CaMn(SiO3)2), Rhodonite ((Mn,Fe,Ca)5Si5O 15 ), Tephroite ((Mn2SiO4)), and some other minerals, have been determined. A global comparison of the characteristics and mineral assemblages of this ore shows strong similarities with the Paleoproterozoic Serra do Navio manganese deposits in Brazil, the Devonian metamorphosed manganese deposits of the South Urals, and the Cretaceous NodaTamagawa Mine in Japan. Based on fieldwork, Mn content and the special mineral assemblages we propose that: (i) the manganeserich rock was possibly deposited in the shallowmarine and marine environment around the Dunhuang ancient block edge areas. The manganese was derived from the continent and the hydrothermal fluid sources. (ii) Subsequently, in a period of regional metamorphism and contact metamorphism, sandstone had metamorphosed into quartz schist, the ores of Rhodochrosite and Pyrolusite and Manganite, as the primary high quality manganese ores, had become into Mnsilicate. (iii) After prolonged supergene weathering, the manganeserich rock presently seen were formed. (iv) The discovery of manganeserich rock indicates that there is a metallogenic geological environment for the formation of manganese deposits in this area.

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赵振明,计文化,李文明,孙吉明,张明祖.2020.北山南部富锰岩石的发现及成因[J].地质学报,94(4):1166-1182.
ZHAO Zhenming, JI Wenhua, LI Wenming, SUN Jiming, ZHANG Mingzu.2020. The discovery and genesis of the manganeserich rocks in the southern Beishan Mountain, China[J]. Acta Geologica Sinica,94(4):1166-1182.

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  • 收稿日期:2019-04-04
  • 最后修改日期:2019-07-25
  • 录用日期:2019-11-07
  • 在线发布日期: 2019-11-07
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