西藏多不杂矿区土壤重金属特征及环境问题防治
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本文由中国地质调查局二级项目“西藏多龙矿床技术经济与环境综合评价”(编号DD20160330)、中国地质科学院基本科研业务费“绿色矿山建设技术装备目录及绿色勘查要求研究”(编号YK1710- 0)联合资助的成果。


Characteristics of soil heavy metals and prevention of environmental problems in the Duobuza mining area, Tibet
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    摘要:

    在矿产开发前,充分了解矿区的土壤重金属环境特征对矿产绿色开发和合理开采具有重要意义。位于西藏改则县的多不杂矿床是多龙矿集区内的重要矿床之一,目前已探明铜资源量达234. 44万吨。本文以多不杂矿区为例,在地表选取4条剖面采集了37件土壤样品,开展了重金属元素(Cu、Pb、Zn、As、Cd、Cr、Hg)含量和pH值测试,对其中10件样品进行了重金属形态特征分析。采用单因子污染指数和内梅罗综合污染指数法分析研究了多不杂矿区内地表土壤重金属的含量、污染指数和形态特征,探讨了重金属元素来源及其对环境的影响程度。结果表明,多不杂矿区地表为碱性土壤,7种重金属元素中,Cu在所有样品中的含量均超过GB156181995Ⅲ级标准;Zn、Cd仅有最大值超过Ⅲ级标准;Pb、As、Cr、Hg含量均不超标。单因子污染指数呈现出Cu>Zn>As>Cd>Cr>Pb>Hg的分布特征,综合指数平均值为11. 60,表明重金属对环境的综合影响程度较高。Cu主要以铁锰氧化态和残渣态存在,分别占48. 40%和14. 73%,Pb、Zn、As、Cr主要以残渣态形式存在,分别占90. 27%、71. 48%、79. 59%、86. 12%。Cd主要以铁锰氧化态和碳酸盐态形式存在,分别占40. 05%和22. 42%,Hg主要以残渣态和腐殖酸态存在,分别占40. 16%和22. 54%。7种重金属元素来源主要有3类:Cu、Zn、Cd、Hg源于黄铜矿的氧化淋滤;Pb、As源于黄铁矿的氧化;Cr源于岩石的自然风化。针对重金属相关的环境问题,提出了针对性的防治建议。

    Abstract:

    Before mineral exploitation, it is of great significance to fully understand the environmental characteristics of soil heavy metals in the mining area for the green exploitation and rational mining. The Duobuza deposit, located in Gaize County, Tibet, is one of the important deposits in the Dulong ore concentration area,and has been proved to contain 2.3444 million tons of copper resources at present. Taking the Duobuza mining area as an example, 37 soil samples were collected from four sections of the earth surface. The contents of heavy metal elements (Cu,Pb,Zn,As,Cd,Cr,Hg) and pH value were tested, and the speciation characteristics of heavy metals in 10 samples were analyzed. Single factor pollution index and Nemero comprehensive pollution index method were used to analyze the heavy metal contents, pollution index and speciation characteristics of surface soil in the Duobuza mining area. The sources of heavy metal elements and their extent of impact on the environment were also discussed. The results show that the surface soil is alkaline. Among the seven heavy metal elements, the contents of Cu in all samples are higher than the GB156181995 Ⅲ standard, only the maximum value of the Zn, Cd exceed the grade Ⅲ standard, the contents of Pb, As, Cr, Hg do not exceed the standard. The single pollution index shows Cu>Zn>As>Cd>Cr>Pb>Hg. The average value of the comprehensive pollution index is 11.60, which shows that heavy metals have a high degree of comprehensive impact on the environment. Cu mainly exists in the form of FeMn oxidation and residual state, accounting for 48.40% and 14.73%, respectively. Pb, Zn, As, Cr exists mainly in the form of residuals, accounting for 90.27%, 71.48%, 79.59% and 86.12%, respectively. Cd in the forms of FeMn oxidation and carbonatestate ,accounting for 40.05% and 22.42%,respectively.Hg in the forms of residual and humic acid state, accounting for 40.16% and 22.54%, respectively. There are three main sources of heavy metal elements: Cu, Zn, Cd, Hg derived from oxidation leaching of chalcopyrite; Pb and As derived from pyrite oxidation; Cr derived from natural weathering of rocks. Aiming at the environmental problems related to heavy metals, some suggestions were put forward for the prevention and control of heavy metals.

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吴宇靓,王松,赵元艺.2019.西藏多不杂矿区土壤重金属特征及环境问题防治[J].地质学报,93(11):2985-2996.
WU Yujing, WANG Song, ZHAO Yuanyi.2019. Characteristics of soil heavy metals and prevention of environmental problems in the Duobuza mining area, Tibet[J]. Acta Geologica Sinica,93(11):2985-2996.

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  • 收稿日期:2018-11-02
  • 最后修改日期:2019-04-22
  • 录用日期:2019-10-14
  • 在线发布日期: 2019-10-24
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