鄂尔多斯盆地北缘侏罗纪延安组、直罗组泥岩微量、稀土元素地球化学特征及其古沉积环境意义
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中国地质调查局天津地质调查中心,中国地质调查局天津地质调查中心,中国地质调查局天津地质调查中心,中国地质调查局天津地质调查中心,中国地质调查局天津地质调查中心,内蒙古地质调查院,核工业二〇八大队,内蒙古地质调查院,内蒙古地质调查院

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国家重点基础研究发展计划(973计划)


Geochemical Characteristics of the Jurassic Yan’an and Zhiluo Formations in the Northern Margin of Ordos Basin and Their Paleoenvironmental Implications
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Tianjin Geological Survey Center of China Geological Survey,Tianjin Geological Survey Center of China Geological Survey,Tianjin Geological Survey Center of China Geological Survey,Tianjin Geological Survey Center of China Geological Survey,Tianjin Geological Survey Center of China Geological Survey,Inner Mongolia Institute of geological survey,208 Geologic Party, China Nuclear Geology, China National Nuclear Corporation,Inner Mongolia Institute of geological survey,Inner Mongolia Institute of geological survey

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    摘要:

    沉积岩的微量元素及稀土元素对沉积环境的水介质变化有着较高的敏感度,是研究古沉积环境及沉积物源构造背景的有效手段。本文采用ICPMS和扫描电镜(SEM)对鄂尔多斯北缘早-中侏罗世延安组、直罗组不同层位的28件泥岩、粉砂质泥岩样品进行了微量、稀土元素测试和粘土矿物分析,结合古生物化石组合及宏观沉积特征,旨在探讨延安组、直罗组氧化-还原条件、源区构造背景及古气候演变对铀成矿的影响。研究表明:①元素B、Sr/Ba、B/Ga组合及U/Th、V/V+Ni、V/Cr、Ni/Co组合指示延安组、直罗组沉积时的古水体介质均为富氧的淡水环境,直罗组古水体盐度相对偏高;Fe2+/Fe3+指示延安组成煤、成岩阶段形成了区域性的原生还原层,而直罗组上段红层为强氧化背景。②沉积学研究表明延安期至直罗期,鄂尔多斯盆地北缘岩相古地理演化经历了河流-冲积扇、湖泊三角洲-沼泽、辫状河-曲流河,Sr、Cu、Sr/Cu、FeO/MnO、Al2O3/MgO等比值和粘土矿物组合垂向变化总体上反映古气候经历了温暖潮湿—干湿交替—干旱-半干旱的转变过程,直罗组底部不整合及上段红层广泛发育期为转换的关键时期;③CIA、ICV指数反映延安组物源区构造环境相对稳定,中侏罗世直罗期,鄂尔多斯盆地周缘构造活动性迅速增强;④沉积岩LaThSc、La/YbΣREE及F1F2判别图解显示本研究区延安组、直罗组沉积物源主要来自上地壳长英质源区,同时具有一定量的碱性玄武岩的混合,其构造背景以大陆边缘型为主,部分物源显示来自大陆岛弧构造背景。以上综合研究表明:延安期-直罗期古气候的转变和富氧古水体条件对本区煤、砂岩型铀大规模成矿作用有着重要的地质意义。

    Abstract:

    Trace elements and rare earth elements (REE) of sedimentary rocks, especially argillaceous rocks, have high sensitivity on hydrological changes of sedimentary environment, therefore, they can be used as an effective method to study paleoclimate and paleoenvironment and trace the source province and tectonic settings during deposition period. In this paper, twentyeight argillaceous rock samples collected from the Jurassic Yan’an and Zhiluo formations in the northern margin of Ordos basin were analyzed for REEs, trace elements and clay minerals by means of ICPMS and SEM analysis to investigate the effect of redox conditions of the Yan’an and Zhiluo formations and structural setting and paleoclimate change of provenance on uranium mineralization. The results shows that (1) the characteristic values and ratios of trace elements and REE such as (B, Sr/Ba, B/Ga), (U/Th, V/V+Ni, V/Cr, Ni/Co) suggest that the bottom water was fresh and oxidation environment during the whole time Yan’an and Zhiluo Formation deposition. Fe2+/Fe3+ ratio suggests that the diagenesis environment of Yan’an Formation was regional reduction block. However, the upper Zhiluo Formation was in a strong oxidized background. (2) The sedimentary sequence from the Lower Jurassic Yan’an Formation to Middle Jurassic Zhiluo Formation represents a complete sedimentary cycle and the sedimentary facies, including fluvialalluvial fan facies(Lower Yan’an Formation), lacuserine deltaswampy facies (Middle and Upper Yan’an Formation),braided stream facies (Lower Zhiluo Formation), meandering river facies(Upper Zhiluo Formation). The Sr, Cu,Sr/Cu, FeO/MnO, Al2O3/MgO ratios and the clay mimerals’ vertical variety indicate that the paleoclimate and paleoenvironment experienced a changing process from warmhumid climate to drywet alternation, arid and semiarid climate. (3) Chemical Index of Alteration (CIA) indices and Index Chemical Variation (ICV) indices reflect that the Yan’an Formation was in relatively stable geotectonic background during middle Jurassic Zhiluo period, until tectonic activities of the margin of Ordos basin started to quickly increase. (4) LaThSc, La/YbΣREE and F1F2 discrimination diagrams indicate that the provenances of Yan’an Formation and Zhiluo Formation were derived mainly from the upper crust (felsic rocks), with a certain amount of alkali basalt addition. The geotectonic background was dominated by continental margin (active continental margin, passive continental margin), and part of material shows a continental island arc setting. The above research results reveal that the transformation of paleoclimate and the oxygencarrying ancient water played an important geological role in formation of coal and sandstonetype uranium mineralization.

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张天福,孙立新,张云,程银行,李艳锋,马海林,鲁超,杨才,郭根万.2016.鄂尔多斯盆地北缘侏罗纪延安组、直罗组泥岩微量、稀土元素地球化学特征及其古沉积环境意义[J].地质学报,90(12):3454-3472.
ZHANG Tianfu, SUN Lixin, ZHANG Yun, CHENG Yinhang, LI Yanfeng, MA Hailin, LU Chao, YANG Cai, GUO Genwan.2016. Geochemical Characteristics of the Jurassic Yan’an and Zhiluo Formations in the Northern Margin of Ordos Basin and Their Paleoenvironmental Implications[J]. Acta Geologica Sinica,90(12):3454-3472.

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  • 收稿日期:2016-12-14
  • 最后修改日期:2016-12-14
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  • 在线发布日期: 2017-01-13
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