西藏多龙矿集区地堡铜(金)矿床年代学、流体包裹体、地球化学特征及其成因类型研究
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中国地质大学北京;;中国地质科学院矿产资源研究所国土资源部成矿作用与矿产资源评价重点实验室,中国地质科学院矿产资源研究所国土资源部成矿作用与矿产资源评价重点实验室,中国地质大学(北京),西藏自治区地质矿产勘查开发局第五地质大队,青海格尔木,816000,中国地质大学北京,中国地质科学院矿产资源研究所国土资源部成矿作用与矿产资源评价重点实验室,北京,中国地质大学(北京)

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Geochronology, Fluid Inclusions, Geochemical Characteristics of Dibao Cu (Au) Deposit, Duolong Ore Concentration Area, Xizang (Tibet), and Its Genetic Type
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China University of Geosciences,Beijing;Institute of Mineral Resources, Chinese Academy of Geological Sciences MRL key laboratory of Metallogeny and Mineral Assessment, Institute of Mineral Resource,Beijing,Institute of Mineral Resources, Chinese Academy of Geological Sciences MRL key laboratory of Metallogeny and Mineral Assessment, Institute of Mineral Resource,Beijing,China University of Geosciences,Beijing,No.5 Geological Party,Tibet Bureau of Geology and Mineral Exploration and Development,Golmud,Qinghai, 816000,China University of Geosciences,Beijing,Institute of Mineral Resources, Chinese Academy of Geological Sciences MRL key laboratory of Metallogeny and Mineral Assessment, Institute of Mineral Resource,Beijing,China University of Geosciences,Beijing

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    摘要:

    多龙矿集区位于班公湖怒江成矿带西段北侧、羌塘地块南缘,是我国近年来发现的最大斑岩浅成低温热液型Cu (Au)矿集区。地堡是多龙矿集区最西南边缘的矿床,资源潜力巨大,有望达到超大型规模,但研究程度薄弱。本次工作对地堡Cu (Au)矿开展了锆石UPb测年、流体包裹体、地球化学等方面的研究,为推动资源勘查和矿集区成矿规律的总结提供理论依据。含矿斑岩锆石206Pb/238U 平均加权年龄为111.2±0.4Ma (MSWD=0.67),与矿集区成矿岩浆活动时限一致,是矿集区重要组成部分。石英脉流体包裹体显示矿床主成矿期成矿流体温度集中于140~382℃,主要集中在240~280℃。成岩阶段石英斑晶中Ⅰ型包裹体盐度范围为0.2%~20.7%NaCleqv,含盐子晶包裹体盐度为33.6%NaCleqv和43.9%NaCleqv;成矿阶段不含石膏石英脉Ⅰ型包裹体盐度范围为0.2%~20.8%NaCleqv,黄铁矿石英脉Ⅰ型包裹体盐度范围为1.1%~11.1%NaCleqv,石膏中Ⅰ型包裹体盐度范围为0.5%~9.3%NaCleqv。对钻孔DNZK6428样品进行主微量元素测试并进行因子分析计算,结果表明F1、F2、F3代表成岩阶段,因子主成分为Y-Ho-Er-Tm-Yb-Dy-Lu-Tb-Eu-Gd-Sm-La-Ce-Pr-Nd-SiO2-Al2O3-CaO等,F4和F5代表铜金矿化阶段,因子主成分为Sn-Sb-Ba-Fe2O3-Sr-|SiO2-Ni-Cu-U-In-Cd-Au-Zn。黄铁矿δ34SV-CDT值总体较为集中,呈“双峰塔式”分布,变化范围为-7.8‰~4.1‰,均值为-4.23‰,为深源岩浆硫,硫的来源接近地幔硫。矿床粒状黄铁矿Co/Ni比值为0.207~10.775,平均值4.39,脉状黄铁矿Co/Ni比值为0.353~23.155,平均值3.802,均为热液成因。矿相学与岩相学研究结果显示矿床具明矾石和硫砷铜矿典型高硫化浅成低温热液矿床的矿物组合,地堡Cu(Au)矿为高硫型浅成低温热液矿床。

    Abstract:

    Duolong ore cluster area, located in the southern Qiangtang terrane, northern Bangong Lake-Nujiang metallogenic belt, is the largest porphyryepithermal copper (gold) ore cluster area discovered in recent years. Dibao is located in the most southwest edge of the Duolong ore cluster area. Despite its good exploring prospect, research work is still weak. To promote resource exploration and provide theoretical basis for metallogenic regularity, we conducted zircon U-Pb dating, fluid inclusions and geochemistry research. The 206Pb/238U weighted average age of 111.2±0.4 Ma (MSWD=0.67) obtained for ore-bearing porphyry is consistent with the mineralization magmatism time limit of the Duolong ore cluster area. The fluid inclusion analysis of quartz vein indicates that ore-forming fluid temperatures of the main metallogenic period range from 140℃ to 382℃, with most focusing around 240℃ to 280℃. In the diagenetic stage, salinity of I-type inclusions from quartz phenocryst ranges from 0.2%NaCleqv. to 20.7%NaCleqv. and mineral-bearing inclusions from 33.6%NaCleqv. To 43.9%NaCleqv. In the metallogenic stage, salinity of I-type inclusions from gypsum-free quartz veins is 0.2%NaCleqv. to 20.8%NaCleqv. and salinity of I-type inclusions from pyrite quartz veins is 1.1%NaCleqv. to 11.1%NaCleqv. Salinity of I-type inclusions from gypsum is 0.5%NaCleqv. to 9.3%NaCleqv. Analysis of main elements and trace elements of drilling DNZK6428 samples and factor analysis results indicate that F1, F2 and F3 represent diagenetic stage and factor principal components are Y-Ho-Er-Tm-Yb-Dy-Lu-Tb-Eu-Gd-Sm-La-Ce-Pr-Nd-SiO2-Al2O3-CaO, F4 and F5 stands for copper (gold) mineralization stage, and factor principal components are Sn-Sb-Ba-Fe2O3-Sr-|SiO2|-Ni-Cu-U-In-Cd-Au-Zn. Pyrite has a centralized δ34SV-CDT range of -7.8‰ to 4.1‰ with an average of -4.23‰, indicating sulfur mainly derived from deep magmatic sulfur, close to mantle sulfur. Granular pyrite has Co/Ni ratios of 0.207 to 10.775 with an average of 4.39, and vein pyrite has Co/Ni ratios of 0.353 to 23.155 with an average of 3.802, indicating that two types of pyrite was hydrothermal genesis. Mineragraphy and petrography study shows a typical mineral assemblage of alunite and enargite, suggesting that the Dibao Cu (Au) deposit belongs to high-sulfidation epithermal deposit.

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乔东海,赵元艺,汪傲,李玉彬,郭硕,李小赛,王松.2017.西藏多龙矿集区地堡铜(金)矿床年代学、流体包裹体、地球化学特征及其成因类型研究[J].地质学报,91(7):1542-1564.
QIAO Donghai, ZHAO Yuanyi, WANG Ao, LI Yubin, GUO Shuo, LI Xiaosai, WANG Song.2017. Geochronology, Fluid Inclusions, Geochemical Characteristics of Dibao Cu (Au) Deposit, Duolong Ore Concentration Area, Xizang (Tibet), and Its Genetic Type[J]. Acta Geologica Sinica,91(7):1542-1564.

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  • 收稿日期:2016-11-16
  • 最后修改日期:2017-04-28
  • 录用日期:2017-04-30
  • 在线发布日期: 2017-07-11
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