气体快速监测系统的组建及其在漠河冻土区天然气水合物钻探工程MK-2孔中的应用
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国家地质实验测试中心,国家地质实验测试中心,国家地质实验测试中心,中国地质调查局油气资源调查中心,国家地质实验测试中心,中国地质调查局油气资源调查中心,新疆维吾尔自治区煤田地质局综合实验室,国家地质实验测试中心

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中国地质调查局地质调查项目(编号GZH201400303)和中国地质科学院基本科研业务费项目(编号YYWF201618)共同资助


Establishment of Gas Rapid Monitoring System and Its Application in Well MK-2 for Scientific Drilling and Exploration of Gas Hydrates in Mohe Permafrost, China
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National Research Center for Geoanalysis,National Research Center for Geoanalysis,National Research Center for Geoanalysis,Oil DdDd Gas Survey, China Geological Survey,National Research Center for Geoanalysis,Oil DdDd Gas Survey, China Geological Survey,Comprehensive Laboratory of Xinjiang Geological Mine Bureau,National Research Center for Geoanalysis

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    摘要:

    本文结合非动力型脱气器与动力型脱气器的优点,研制出一种适用于低流量、低流速等小型钻探工程的飞溅离心式钻井泥浆脱气设备,并组建一套陆域天然气水合物钻井气体的快速监测系统。此套系统中,钻井泥浆在脱气筒内自动采集气体并将气体样本通过导管引入实验室,通过阀切换、多柱分离、双检测器的气相色谱分析系统,可同时检测CH4、C2H6、C2H4、C3H8、C3H6、n-C4H10、i-4H10、n-C5H12、i-C5H12、O2、N2、CO2、CO等多种气体。其中,烃类气体的方法检出限为0.10~1.00 μL/L,非烃气体的检出限为100 μL/L~0.01%,方法精密度为1.65%~11.6%,样品分析周期约10 min。该系统通过在黑龙江省漠河盆地开展的东北冻土区天然气水合物科学钻探工程MK2孔的试运行,实现了钻井气体的在线快速监测,方法灵敏、稳定可靠,具有较好的精密度和较低的检出限,能够基本满足天然气水合物等气体钻探现场检测的需要。

    Abstract:

    This study, combined with the advantages of both nondynamic degasser and dynamic degasser, developed a smallsized centrifugal splash degasser characterized by low flow amount and low flow velocity, and thus established a set of fast monitoring system which can be used for monitoring drilling gas of continental gas hydrate. In this system, gases is collected automatically from drilling mud in a degassing tube, inlet into field laboratory using tubes, and analyzed with the gas chromatographic analyzing system. This system can analyze a wide range of gases, such as CH4, C2H6, C2H4, C3H8, C3H6, nC4H10, iC4H10, nC5H12, iC5H12, O2, N2, CO2 and CO. Among them, the low limits for hydrocarbon gases and nonhydrocarbon gases are 01 to 100 μL/L and 100 μL/L to 001 %, respectively. The gas monitoring precision is lower than 116 with the detection limits ranging between 010~100 μL/L, and an analysis cycle of about 10 minutes. This rapid gas monitoring system has passed through the trial run in Well MK2 for Scientific Drilling and Exploration of Gas Hydrates in the Mohe permafrost, thus realizing the live fast monitoring for drilling gas. The results show that this system is sensitive, stable and reliable, and is of better precision and low detection limit. Therefore, this system can basically meet the requirement of onsite monitoring.

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李松,刘晨,饶竹,赵省民,佟柏龄,邓坚,杨峰.2017.气体快速监测系统的组建及其在漠河冻土区天然气水合物钻探工程MK-2孔中的应用[J].地质学报,91(9):2131-2138.
LI Song, LIU Chen, RAO Zhu, ZHAO Xingmin, TONG Bailing, DEN Jian, YANG Feng.2017. Establishment of Gas Rapid Monitoring System and Its Application in Well MK-2 for Scientific Drilling and Exploration of Gas Hydrates in Mohe Permafrost, China[J]. Acta Geologica Sinica,91(9):2131-2138.

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  • 收稿日期:2016-03-07
  • 最后修改日期:2017-02-13
  • 录用日期:2017-02-23
  • 在线发布日期: 2017-09-14
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