含膏盐地层与矽卡岩铁矿的关系:以湖北金山店铁矿为例
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国家重点基础研究计划973专题(2012CB416802)、国土资源部公益性行业科研专项经费课题(200911007-18)和中国地质调查局地质矿产调查项目(12123311035)


The relationship between the evaporate and ore-forming process of Jinshandian iron skarn deposit
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    摘要:

    含膏盐地层对金属矿床的形成起到了重要的作用。本文通过对金山店铁矿方柱石和硬石膏、石膏、黄铁矿矿物成分开展研究,结果表明方柱石中Cl含量高达4%,硬石膏、石膏、黄铁矿δ34S值分别为24.9‰~27.9‰(n=10)、27.5~28.4‰(n=2)和16.2‰~19.4‰(n=9),硬石膏和石膏δ34S值总体上接近中三叠统地层沉积硬石膏的δ34S值,而黄铁矿δ34S值则明显偏离0值,暗示金山店铁矿成矿体系中的S主要来自于含膏盐地层。根据共生的硬石膏和黄铁矿矿物对S同位素组成平衡分馏方程计算出其“平衡温度”范围为563~728℃(n=6),高于硬石膏中流体包裹体均一温度。已有资料暗示在高温岩浆热液阶段或是更早的岩浆阶段,含膏盐地层中的膏盐矿物就已经大量加入金山店铁矿成矿体系之中。根据方柱石中Cl的含量估算出平衡流体中的盐度超过70%,高盐度流体具有萃取和搬运巨量铁质的能力,同时提高了硬石膏的溶解度。大量硬石膏加入成矿体系,提高了该体系的氧化性,为后期磁铁矿的形成提供了良好的条件。

    Abstract:

    Evaporate, composed dominantly of varying proportions of halite, anhydrite and gypsum, have showed strong relationship with the ore-forming process, especially the magmatic-hydrothermal related deposit, but its detail affect have not been studied. Jinshandian iron skarn deposit has obvious minerals assemblages like anhydrite, gypsum, pyrite and scapolite, which were resourced from evaporate. The ranges ofδ34S values for evaporate related minerals are +16.2‰~+19.4‰ for pyrite(n=9), +24.9‰~+27.9‰ for anhydrite(n=10) and +27.5~+28.4‰(n=2)for gypsum, the latter two are closed to the strata of the Middle Triassic Series at the Middle Low Yangze River, suggesting that the evaporate had mainly offered sulfur for the ore-forming system. Sulfate–sulfide mineral fractionation is consistent with an approach to isotopic equilibrium, and calculated temperatures for coexisting anhydrite–pyrite pairs (n=6) are 563℃~728℃, which is much more higher than the temperatures gotten from fluid inclusions. Existing data shows that evaporate had joined in the ore-forming system at the stage of high temperate magmatic-hydrothermal or maybe more earlier. Cl content in scapolite are as high as 4%, indicated NaCl equiv (wt%) of the fluid could have reached 70%. Dissolution of evaporate have the effect of increasing the salinity of the fluid, which enhanced the capacity of leaching and transporting iron and the solubility of anhydrite. With amount of anhydrite joining in the ore-forming system, the oxidation state of the system were changed obviously, which was need by large amounts of magnetite depositing.

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朱乔乔,谢桂青,王建,李伟,于炳飞.2013.含膏盐地层与矽卡岩铁矿的关系:以湖北金山店铁矿为例[J].地质学报,87(9):1419-1429.
zhuqiaoqiao, xieguiqing, wangjian, liwei, yubingfei.2013. The relationship between the evaporate and ore-forming process of Jinshandian iron skarn deposit[J]. Acta Geologica Sinica,87(9):1419-1429.

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  • 收稿日期:2013-05-27
  • 最后修改日期:2013-08-16
  • 录用日期:2013-08-18
  • 在线发布日期: 2013-09-13
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