长江水中悬浮物含量与矿物和化学组成及其地质环境意义
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国家自然科学基金项目(面上项目,重点项目,重大项目)


The Contents and Mineral and Chemical compositions of Suspended Particulate Materials in the Changjiang River, and Their Geological and Environmental Implications
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    摘要:

    在2003~2007年间,在长江干流的25个水文站及主要支流的13个水文站系统采样,对悬浮物的含量及其矿物与化学组成系统地进行了测定。根据这些数据,对长江悬浮物的矿物和化学组成的时空变化及其地质与环境意义进行了系统研究。 本次所采样品中悬浮物含量平均值为256.5mg/L,在世界各大河中居于中等水平。悬浮物含量呈现大幅度的时空变化,与水流速度、径流量及泥沙供给情况的变化相对应,受河床坡度、降雨量、风化强度、侵蚀情况及人工活动等多种因素的影响。近年来,长江悬浮物含量逐渐下降,与上游的退耕还林和水库建设密切相关。特别是三峡水库工程引起泥沙在库区大量沉积,显著降低河水的悬浮物含量,导致其下游河段堤岸冲刷加剧,洞庭湖、鄱阳湖和长江口的沉积减少。这种变化带来的环境效应巨大,需要慎重评估和应对。 长江水中悬浮物主要由粘土矿物、碎屑硅酸盐矿物和碎屑碳硅酸盐矿物组成,并含有少量重矿物、氢氧化物和有机物。与黄河悬浮物矿物组成的对比研究表明长江流域的化学风化作用明显强于黄河流域,而物理侵蚀作用明显弱于黄河流域。由上游到下游,长江悬浮物中粘土和碎屑硅酸盐矿物逐渐增高,而碎屑碳硅酸盐逐步降低,与中下游地区气候变得湿热,化学风化变强的情况相对应。 与上地壳岩石平均值相比,长江悬浮物的SiO2、CaO、K2O 、Na2O含量较低,而TFe2O3含量较高,反映硅酸盐矿物化学风化过程中部分硅、钾、钠、钙的流失和铁的富集。与全球河流悬浮物和黄河悬浮物相比,长江悬浮物的SiO2、Na2O含量较低,反映长江流域的化学风化作用较强。与长江水系沉积物相比,长江悬浮物的SiO2、Na2O含量较低,而Al2O3、K2O 、MgO、TFe2O3较高,反映悬浮物比较富含粒度较小的粘土与铁质成分。从上游往下游,长江悬浮物中CaO、MgO含量逐渐降低,SiO2 含量逐步升高,与粘土矿物含量增高和碳酸盐含量降低的趋势相对应。 长江悬浮物中Co、Ni、Cu、Zn、Pb、Cd含量均高于上地壳岩石的平均含量,可能由这些元素在风化过程优先为粘土所吸附所引起。在攀枝花、宜宾、九江、大通、南京等站悬浮物中发现的铜、铅、锌的高含量,可能均与相关地段采矿活动有关。2005年7月在富顺和长沙发现Cd的高异常值引人注目。悬浮物中Cu、Pb、Zn、Cd的含量较长江水系沉积物的平均含量高出数倍、乃至数十倍,可能反映近年来流域采矿活动加剧,其对流域环境的长远影响值得关注。 长江悬浮物的稀土总量与全球页岩的平均值相比略显偏高。长江悬浮物的REE分布形式于上地壳基本一致,表明长江流域出露的岩石的化学组成与上地壳岩石平均组成没有明显差别,而且岩石风化过程中稀土元素未出现明显分馏。

    Abstract:

    The contents and mineral and chemical compositions of the SPM in the Changjiang River were determined on the samples collected from 25 hydrological stations in the mainstem and 13 hydrological stations in the major tributaries during 2003~2007. Based on these data, the spacial and temporal variations of mineral and chemical compositions in Changjiang SPM, and their geological and environmental implications were systematically investigated. The samples collected in this study have an average SPM content of 256.5mg/L, which is moderate in the world large rivers. Large spacial and temporal variations of SPM contents are observed in the Changjiang River, corresponding to the changes of flow speed, runoff and SPM supply, which are effected by the factors, such as the slope of the river bed, local precipitation, weathering intensity, erosion conditions and anthropogenic activities. The SPM contents in the Changjiang River reduce gradually in recent years, reflecting the effects of tree planting and dam-building in its upper reaches. Especially in the Three Gorge Reservoir prominent sedimentation causes significant reduction of SPM contents, which leads to increase of embankment washout in its lower section, reduction of sedimentation in the Dongting Lake and Poyang Lake, as well as in the estuary area. The environmental effects of these changes will be very significant and should be evaluated and treated carefully. The SPM of the Changjiang River consists of clay minerals, clastic silicate and carbonate minerals, some heavy minerals, iron hydroxide and organic compounds. A comparison between the mineral composition of SPM in the Changjiang River and that in the Yellow River indicates that the chemical weathering activity in the Changjiang River area is much more intensive than in the Yellow River area, and the physical weathering activity in the Changjiang River area is less intensive than in the Yellow River area. From upper reaches to lower leaches, the contents of clay and clastic silicate in the Changjiang River SPM increase gradually, but the content of carbonate minerals decrease gradually, corresponding to the wetter and hotter climate and more intensive chemical weathering in the middle and lower reaches. In comparison with the upper crust rocks, the SPM in the Changjiang River has lower contents of SiO2、CaO、K2O and Na2O and higher contents of TFe2O3, reflecting preferential loss of Si、Ca、K and Na and enrichment of Fe in chemical weathering processes of silicates. In comparison with the world river and the Yellow River, the SPM of the Changjiang River shows higher contents of SiO2 and Na2O, indicating its higher intensity of chemical weathering. Compared with the sediments of the river beds, the Changjiang River SPM has lower contents of SiO2 and Na2O, and higher contents of Al2O3、K2O 、MgO and TFe2O3, reflecting the enrichment of the smaller particles of clay and iron hydroxide in SPM. From the upper reaches to lower reaches, the CaO and MgO contents in SPM decrease gradually, but the content of SiO2 increase gradually, corresponding to the increase of clay minerals and decrease of the carbonates. The Co、Ni、Cu、Zn、Pb and Cd contents in the Changjiang River SPM are all higher than those of the upper crust rocks, which may be caused by their preferential adsorption by clay mineral in weathering processes. High Cu, Pb and Zn contents in SPM of Panzhihua, Yibin, Jiujiang, Datong and Nanjing stations may be related to the local mining activities. Remarkable high Cd anomalies are found in the Fushun and Changsha stations during July 2005. Campared with the bed sediments, the Cu、Zn、Pb and Cd contents in the Changjiang River SPM are several times to several tens of times higher, probably reflecting more intense mining activities in recent years, which should be considered in evaluation of the long term environmental variation of the drainage area. The total REE contents in SPM of the Changjiang River are slightly higher than that of the average world shale. The REE distribution pattern of Changjiang River SPM is similar to that of upper crust, indicating that the rocks exposed in the Changjiang River basin have similar chemical compositions with average crust rocks, and no obvious fractionation on REE has appeared in the weathering process.

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丁悌平,高建飞,石国钰,陈峰,王成玉,韩丹,罗续荣.2013.长江水中悬浮物含量与矿物和化学组成及其地质环境意义[J].地质学报,87(5):634-659.
Ding Tiping, Gao Jianfei, Shi Guoyu, Chen feng, Wang Chengyu, Han Dan, Lou Xurong.2013. The Contents and Mineral and Chemical compositions of Suspended Particulate Materials in the Changjiang River, and Their Geological and Environmental Implications[J]. Acta Geologica Sinica,87(5):634-659.

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  • 收稿日期:2012-09-03
  • 最后修改日期:2012-12-17
  • 录用日期:2012-12-18
  • 在线发布日期: 2013-05-03
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