The paper analyzes the chemical composition and trace elements of the Shuanghe marble rock and also studies on confirming the point position of the Metamorphic and metamorphic complex zircon by CL zircon image. The dating result as follows: 1) The older core \"inherited zircon\" in the metamorphic complex zircon were measured 32 points ranging from 2357Ma to 342Ma, among these 15 belong to Proterozoic era with the age range from 2357Ma to 572Ma and 17 are Paleozoic from 524Ma to 342Ma. 2)8 points had been made in the Metamorphic zircon and 5 in which within the scope of 249Ma to 234Ma corresponding to the UHP time, furthermore age ranging at 228Ma ~221Ma are retrograde time. Above all, the existing of a large number of Paleozoic magmatic inherited zircon indicates the original rock of the Shuanghe marble rock will not earlier than the Paleozoic era.